Diazo compounds play an important role as reaction intermediates and reagents in organic synthesis. This book is a critical, well- referenced and eminently readable introduction to the chemistry of aliphatic, inorganic and organometallic diazo compounds. It provides well-researched information that could otherwise be obtained only by costly and time-consuming searches of multi-volume treatises and the original literature.
Topics covered in depth include:
– preparation and structure of diazo compounds
– kinetics and mechanism of diazotizations
– reactions of diazo compounds
– applications in organic synthesis
– metal complexes with diazonium and diazo compounds
Many tables and reaction schemes as well as copious literature citations make this book a highly valuable reference work for synthetic organic chemists, inorganic chemists, organometallic chemists and industrial chemists.
Already available: Volume 1 of Diazo Chemistry covering aromatic and heteroaromatic compounds.
Content:
Chapter 1 Introduction (pages 1?10):
Chapter 2.1?2.5.2 Methods for the Preparation of Alkane, Alkene, and Alkyne Diazo Compounds: Section 2.1?2.5.2 (pages 11?45):
Chapter 2.5.3?2.11 Methods for the Preparation of Alkane, Alkene, and Alkyne Diazo Compounds: Section 2.5.3?2.11 (pages 46?94):
Chapter 3 Inorganic Diazo Compounds and Metal Complexes with Dinitrogen as Ligand (pages 95?119):
Chapter 4 Kinetics and Mechanism of Aliphatic Diazotization (pages 121?143):
Chapter 5 The Structure of Aliphatic Diazo Compounds (pages 145?189):
Chapter 6 Reactions of Aliphatic Diazo and Diazonium Compounds Not Involving Initial Dediazoniation (pages 191?240):
Chapter 7.1?7.4 Dediazoniation Reactions Involving Diazonium Ion Intermediates: Section 7.1?7.4 (pages 241?277):
Chapter 7.5?7.8 Dediazoniation Reactions Involving Diazonium Ion Intermediates: Section 7.5?7.8 (pages 278?304):
Chapter 8.1?8.5 Dediazoniation Reactions Involving Carbene and Carbenoid Intermediates: Section 8.1?8.5 (pages 305?344):
Chapter 8.6?8.8 Dediazoniation Reactions Involving Carbene and Carbenoid Intermediates: Section 8.6?8.8 (pages 344?381):
Chapter 9 Miscellaneous Reactions Involving Diazo and Related Compounds (pages 383?419):
Chapter 10 Metal Complexes of Diazonium and Diazo Compounds (pages 421?454):
Chapter 11 Epilogue: From Peter Griess’ Discovery to Organometallic Diazo Compounds (pages 455?458):
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