[PDF] Relaxometry of water-metal ion interactions van Eldik R. (eds.)

Content: Cover — ADVISORY BOARD — copyright — table of contents — PREFACE — ERRATUM — INTRODUCTION: GENERAL THEORY OF NUCLEAR RELAXATION — I. What is Nuclear Relaxation? — A. LONGITUDINAL RELAXATION — B. TRANSVERSE RELAXATION — C. THE ROTATING FRAME … — D. CROSS-RELAXATION … — E. CROSS-CORRELATION … — II. Relaxation Mechanisms — A. INTERACTION WITH RAN … — B. RELAXATION BY CHEMIC … — C. SCALAR RELAXATION OF … — D. RELAXATION BY DIPOLAR … — E. QUADRUPOLAR RELAX … — III. Water NMRD in Diamagnetic Systems — A. PUREWATER — B. WATER IN PROTEIN SOL … — REFERENCES 1 — NMR RELAXATION IN SOLUTION OF PARAMAGNETIC COMPLEXES:RECENT THEORETICAL PROGRESS FOR S=1 — I. Introduction — II. The ”Classical” Theory — A. THE SOLOMONB?LOEMB … — B. THE MODIFIED SOLOMON … — C. VALIDITY OF THE POINT- … — D. THE REDFIELD RELAX … — III. The Curie-Spin Relaxation and Related Topics — A. THE CURIE-SPIN RELAX … — B. PARAMAGNETIC CROSS … — IV. The General (Slow-Motion) Theory — A. THE REDFIELD LIMIT AND … — B. THE LATTICE AND THE ZFS — C. THE EFFECTS OF ZFS … — V. Electron Spin Relaxation and the PRE in Some Limiting Cases — A. HIGHLY SYMMETRIC SYS … — B. SLOWLY-ROTATING, LOW … — C. RAPIDLY-ROTATING SYS … — D. ELECTRON SPIN DYNA … — VI. Spin-Dynamics Models — VII. Outer-Sphere Relaxation — A. GENERAL ASPECTS — B. OUTER-SPHERE PRE AND … — C. OUTER-SPHERE RELAX … — D. CHEMICAL EXCHANGE — VIII. Molecular Vibrations, Electron Spin Relaxation and the PRE — IX. Concluding Remarks — ACKNOWLEDGMENTS 2 — REFERENCES 2 — 1H NMRD PROFILES OF PARAMAGNETIC COMPLEXES AND METALLOPROTEINS — I. From the NMRD Profile to the Electron Relaxation Mechanism — A. DEPENDENCE OF THE … — B. THE ORIGIN OF ELECT … — C. ELECTRON RELAXATION … — II. From the NMRD Profile to the Structural and Dynamic Parameters — A. DEPENDENCE OF THE … — B. COPPER COMPLEXES … — C. IRON COMPLEXES AND … — D. MANGANESE COMPLEX … — E. OTHER TRANSITION … — F. GADOLINIUM COMPLEXES … — III. Magnetic Coupled Systems — A. NUCLEAR AND ELECT … — B. EXAMPLES — IV. Conclusions — ACKNOWLEDGMENTS 3 — REFERENCES 3 — Gd(III)-BASED CONTRAST AGENTS FOR MRI — I. General Remarks — II. Contributions to the Relaxivity — A. INNER-SPHERE CONTRI … — B. OUTER-SPHERE CONTRI … — C. SECOND-SPHERE CONTR